What is Aluminum Anodizing? Explore Everything!

Aluminum has many excellent properties. Its cost-effectiveness makes it suitable for many manufacturing projects. However, its corrosion resistance and aesthetics are not as good as one would love. So, many manufacturers put this material under an anodizing process. But do you know: what is aluminum anodizing?

 

I know that this concept is well understood. That’s because fewer manufacturers use this technique to enhance the properties of aluminum. It benefits by increasing corrosion resistance and aluminum’s physical appearance and look. In this article, we’ll discuss aluminum anodizing most easily. So, let’s get rolling!

 

What Does Anodized Mean?

It is an electrochemical process that gives the metal surface the final touch. The purpose of anodizing is to provide a uniform oxide layer on the surface. This oxide layer has many benefits. The primary ones include corrosion resistance, which protects the elegance of metal.

 

Anodizing is a technique that is applied to many metals. As I said, it is an electrochemical process. This is done by passing a current through a chemical to impart an oxide layer on the metal. You might argue that many metals naturally make oxide layers. You’re right, but that oxide layer is not very strong.

 

So, this oxide layer undergoes deterioration quite quickly. So, the metal becomes exposed and vulnerable to different environmental conditions. The issues such as fading, corrosion, and quality degradations become evident. However, the anodization adds another strong oxide layer. It is stronger than the natural oxide layer. So it protects the metal better.

 

What is Aluminum Anodizing?

Aluminum anodizing is adding an oxide layer to the surface of aluminum. This additional layer protects aluminum from corrosion. This is done by passing current to the acid bath and dipping aluminum in this solution. The added oxide layer is very durable and aesthetically pleasing. 

 

In simple words, aluminum anodization is an electrolytic process. The main benefit of this process is that it thickens and smoothens the surface. It forms a uniform oxide layer on the top of the aluminum, enhancing its rigidity and appeal. First invented in 1923, aluminum anodizing is known as the Bengough-Stuart process. 

 

It was first used to protect Duralumin seaplanes against corrosion. The question is: Is the anodization process effective against corrosion? The answer is YES. Generally, aluminum forms an aluminum oxide layer when it comes in contact with oxygen. However, this aluminum oxide layer is not very durable. It saves aluminum from corrosion for a short period.

 

After that, it starts to deteriorate. Once it has deteriorated, corrosion takes on aluminum and damages it. However, the anodizing process allows manufacturers to add an artificial oxide layer. This layer is stronger, thicker, and more durable than aluminum oxide. It does not deteriorate quickly, so it keeps protecting aluminum against corrosion for a long time.

 

Not only does it enhance corrosion resistance, but it also improves aesthetics. How? The manufacturers add different dyes during the anodization process. These dyes add color to the oxide layer, enhancing the shine and look of the aluminum. Many manufacturers use anodized aluminum to make decorative products.

 

How to Anodize Aluminum?

In the above section, we discussed the overview of the anodization process. Have you got the basics of what anodization of aluminum is? Let’s discuss some more advanced information and learn how aluminum is anodized. This section will help you understand the step-by-step process with all the minute details.

 

1- Surface Preparation by Cleaning

 

The first step starts by preparing the metal surface. In this step, the metal is thoroughly cleaned with the surfactant. The surfactant removes dust and dirt from the surface. At the same time, it tackles the natural oxide layer, easing the process further.

 

The first step in surface preparation is to clean the aluminum surface. You can do this using an alkaline detergent or solvent. While cleaning, you should ensure that no dirt or contaminants remain. If dirt is left, it will affect the quality of the added layer of oxide.

 

Later, the metal is etched to create a uniform surface using sodium hydroxide. The NaOH solution dissolves the outer layer of the anode, removing surface irregularities. The last step is Desmutting, which removes any residue from the surface. It is an easy process that can be achieved using nitric acid. As a final step, it ensures effectiveness.

 

2- Preparation of Electrolyte or Acid Bath

 

As I said earlier, the anodizing process is done through a solution. The electric current is passed through this solution. This solution mainly consists of sulphuric acid. So, the layer is added by immersing the aluminum in the electrolyte tank. So, it is key to prepare the acidic solution. 

 

Sulfuric acid is generally used as an electrolyte because of its electroconductivity. The aluminum rod acts as a positive electrode called the anode in the system. Another non-conductive material, like carbon, is used for cathode or negative electrodes. Oxygen ion (negatives) goes on the anode (made of aluminum) when the current passes through this solution.

 

3- Passing the Electricity Through the Solution

 

Once the electrolyte chamber is ready, pass the electricity. Electricity acts as a key component. Passing a direct current stimulates chemical reactions within the acid tank. Soon, the aluminum atoms lose their electrons. Positively charged aluminum ions combine with negative oxygen ions, forming aluminum oxide. 

 

This newly made aluminum oxide layer is robust and durable. That’s how a protective coating is formed on the surface. The oxide layer is thin and non-porous at the start, which develops later. As the process continues, the layer grows thicker and stronger. It also forms tiny pores on the surface that act as absorbent in later stages.

 

4- Post Process of Aluminum Anodizing

Using the steps mentioned above, you’ll have new aluminum oxide layers on the aluminum surface. However, there are some additional steps that you should follow. Keep in mind that these steps are not mandatory. But they help enhance the look and uniformity of the newly made oxide layer. In the section below, I’ll discuss those steps.

 

1- Adjusting thickness

The thickness of the oxide layer matters the most. It defines how strong or durable the oxide layer would be. The thickness of the oxide membrane depends on the tank’s temperature and duration. You can adjust the thickness of the oxide by fluctuating the electric current. 

The intensity of the electricity passed determines the volume of the final product. You can increase the thickness if you want an incredibly durable layer and vice versa. But remember, it would also increase the weight of the aluminum part. If you make a lightweight product, keep the thickness of the layer lower. 

 

2- Coloring Or Dying

Coloring is optional, and many products don’t need it. However, it enhances the aesthetics, giving the product a contemporary touch. In most cases, the metal undergoes the dip coloring method for the desired outcome. The liquid color dye penetrates deeper into the metal through the porous oxide layer. This eases the color transfer process and strengthens the dye and surface.

Quick Highlight: If you’re making any product for decorative purposes, you should use coloring. Why? Because it enhances the look and charm of the product. However, if you focus on practicality, coloring is unnecessary. Having the oxide layer is good enough to give you optimal performance.

 

3- Closing the Pores

During the anodizing process, some pores are left on a layer of oxide. These pores should be sealed or closed correctly to avoid any durability issues in the oxide layer. Sealing helps in closing those pores effectively. Interestingly, there are different types of sealings available. Some of those are as follows:

• Hot Sealing
• Mid-Temperature Sealing
• Cold-Temperature Sealing

 

Hot sealing involves extremely heated deionized water that closes the pores on the top surface. The excess temperature swells the oxide, effectively sealing the pores. On the other hand, mid-temperature sealing uses nickel acetate solutions heated between 60 and 80 degrees Celsius. 

 

Last but not least, cold temperature sealing is the most energy-efficient method. It utilizes cobalt salts at low temperatures to seal the oxide layer. It is best for sensitive machine parts. Want to know about the best method? I recommend mid-temperature sealing. Why? Because it helps achieve a balance between effectiveness and energy consumption.  

 

What Should I Pay Attention to When Anodizing Aluminum?

 

I know that process of anodizing is simple and easy to execute. However, the slight mistake can affect the quality of the newly made oxide layer. There are a few things that you must keep in mind while following the process of anodizing. Let’s discuss those things that you pay heed to: 

 

1- Do a Good Job of Cleaning After Coloring

 

If the surface of the aluminum parts is not cleaned, the residual color paste will affect the aluminum products. I recommend that you always clean the surface once you have colored it.

 

2- Pay Attention to the Cleaning Before Coloring

 

The anodizing tank must be cleaned thoroughly after use, especially the gaps in aluminum parts. Otherwise, the residual acid and alkali will gradually flow out during the coloring process. This will cause the pH of the coloring solvent to be beyond the normal range. This will cause the coloring of the aluminum surface to be more uneven and rough. In the worst case, the surface could rust or oxidize instead of achieving the desired clean, white finish.

 

3- Aluminum Parts Can Not Be Stacked & Placed During Coloring

 

During the coloring process, the aluminum parts cannot be superimposed. Ideally, they must be placed in parallel. Otherwise, the yin and yang surfaces will be generated due to the occlusion of the superimposed position.

 

4- Timely Coloring After Anodizing Treatment

 

The aluminum parts should be colored in time after anodizing treatment. If the aluminum parts are exposed to the air too long after anodizing, the film layer’s gap will shrink. It may get dirty, causing problems with coloring. If the coloring tank is too small, I recommend immersing the aluminum products in clean water when coloring in batches.

 

Factors That Influence the Properties of the Aluminum Oxide Layer in Anodization

The aluminum anodizing process is very effective. It gives an oxide layer of excellent strength and durability. However, some factors can influence the quality of the anodized layer. Understanding those factors is key to a better aluminum oxide layer. So, let’s dive deep and discuss those factors.

 

1- Electrolyte Composition

Electrolytes affect the properties of the oxide layer. For example, chromic acid can produce a thinner layer than sulfuric acid. However, sulfuric acid is versatile and offers more general-purpose applications. I recommend using sulfuric acid for the aluminum anodizing process.

 

2- Duration

The duration of the anode in the electrolyte determines the density of the oxide shield. In general, the longer the duration, the denser the coating. If you want a strong layer, give the anode more time in the electrolyte.

 

3- Electric Current

Electric current is another critical factor in the process. It affects the uniformity and thickness of the oxide layer. In general, higher current density speeds up layer formation. Also, high density can affect uniformity and result in rough patches.

 

4- Temperature

The electrolyte’s temperature affects the aluminum anodization process. Lower temperatures generally produce more rigid resistance, while high temperatures enhance the porosity. Hence, you can choose the temperature control according to your requirements. I recommend keeping the temperature in balance. Increasing the temperature would cause more pores in the layer.

 

Different Types of Aluminum Anodizing

The aluminum anodizing process has been around for almost a century. Initially, it had many limitations and drawbacks. However, things have evolved, as has the way they are done. There are three significant types of aluminum anodizing. Here are their names:

 

• Chromic Acid Anodizing
• Sulfuric Acid Anodizing
• Hardcoat Anodizing

 

Each of these anodization types has unique perks. Some people consider chromic acid anodizing to be the best. However, the majority favor sulfuric acid anodization. Let’s discuss each of these types with more details and explanations.

 

1- Chromic Acid Anodizing

It is the ancient yet most effective aluminum anodization method. In the early days, this process was most popular. It used to involve chromic acid in the making of electrolytes. What makes it different is its ability to produce the thinnest oxide coating. The chromic acid solution can create a protective oxide layer ranging from 0.00002 to 0.0001 inches.

However, there are some limitations when creating a thicker and robust oxide layer. For example, some products need a thick oxide layer. Why? Because thicker layers offer better corrosion resistance. However, it can be a good option for making decorative products. The thin layer would enhance aesthetics. 

 

2- Sulfuric Acid Anodizing

I consider sulfuric acid anodizing to be the best of all the types. It is one of the most versatile and affordable anodization methods. This method uses sulfuric acid to make the electrolyte. It helps us achieve the oxide layer between 0.0002 and 0.001 inches.

It won’t be wrong that this type is one of the most used. Many electrical appliances and automotive tools rely on this type. Interestingly, sulfuric acid anodizing has further subtypes. Those are as follows:

• Boric-Sulfuric Acid Anodizing
• Thin Film Sulfuric Acid Anodizing

Boric-Sulfuric Acid Anodizing uses boric-sulfuric acid. The primary benefit of this method is that it replaces traditional toxic chromium ions. It also enhances the sustainability and affordability of anodizing processes. In general, this method is preferred when meeting environmental considerations is essential.

On the other hand, the Thin Film Sulfuric Acid Anodizing is more like chromic acid anodizing. How? Because it produces a thin oxide layer. However, don’t confuse it with chromic acid anodizing, as it does not use chromic acid in electrolytes. Using it to make a strong product won’t be a wise decision. Their selection depends on the type of your project. 

 

3- Hardcoat Anodizing

The last type is hard coat anodizing, which is generally suitable for heavy-duty products. It produces a dense and thick oxide shield on the metal, which can easily protect the product from corrosion even in very harsh conditions.

Even though this method uses sulfuric acid in the electrolyte chamber, the difference lies in thickness. The approach can create a thick layer between 0.0005 and 0.002 inches. The technique is ideal for materials such as defense parts demanding extraordinary resistance. The process enhances the metal’s hardness, protecting it from weather extremes.

 

How to Tell if Aluminum is Anodized?

 

The simplest way to identify aluminum anodization is to look at the surface. If you notice a firmer oxide layer, it indicates aluminum is anodized. However, this is not as simple as aluminum itself makes a natural aluminum oxide layer. So, how would you know if the anodization layer is relatively thin? Don’t worry; here are a few ways that you can use to know if aluminum is anodized:

 

• Visual Appearance: Anodized aluminum always has a shiny and matte look. However, natural aluminum does not have that shine. This shine or matte look comes due to an artificial layer of oxide added as a result of the anodization process.
• Water Test: This is the simplest way of identifying aluminum and costs literally nothing. The anodization process adds a layer on the surface of aluminum. This layer is hydrophobic, meaning it repels water. You should put a drop of water on the aluminum. If water spreads on the surface, it implies aluminum is not anodized. If the water beads up, it indicates aluminum is anodized.
• Conductivity Test: The layer added by anodization is an insulator in nature. It means it offers resistance when it comes to electricity conductivity. You can test aluminum by exposing it to electricity. Use a multimeter to check conductivity. If aluminum conducts electricity, it is not anodized, and vice versa.
• Sodium Hydroxide Test: The artificial oxide layer added by aluminum does not react with anything. You can put a few drops of sodium hydroxide on the surface of aluminum. If aluminum keeps its color and doesn’t react, it means it is anodized. Remember, raw aluminum will react with this chemical and lose its color.

 

Benefits and Limitations of Aluminum Anodizing

There are certain limitations and drawbacks associated with aluminum anodization. Here is a table showing the pros and cons of this process:

 

Advantages	Drawbacks
Improved corrosion resistance.	Slight difference in aluminum composition in the final material.
Enhanced the longevity of the final product.	Slight difference in final dimensions, which might affect precision applications.
Colorful visual appeal.	Change in anodized aluminum finish; may not always match expectations.
Smooth final texture.	Anodizing can make the process more costly for small-scale or one-off projects.
Easy to clean and maintain.	Compatibility issues with different aluminum alloys. For a smooth experience, you’ll have to consider many factors.

Modern-day Applications of Anodized Aluminum 

 

The aluminum anodized parts are used in different fields and industries, including:

 

• Aerospace: For constructing precise and lightweight aircraft parts.
• Electronics: For creating machines and instruments with fine texture and radiance.
• Healthcare: Anodized parts are used in implants and other instruments.
• Automobile: For creating durable and leveled parts of vehicles and cars.
• Defense and Construction: For building weather-resistant tools and equipment.
• CNC Machining Services: One of the most common uses of anodization is in CNC machining. It offers the desired superior surface finish options in CNC services. The Aluminum CNC machining service provider uses anodization to craft custom parts with thicknesses between 0.002mm and 0.04mm.

 

Aluminum Anodizing and CNC Machining

Undoubtedly, aluminum is a multipurpose metal. It has applications in different industries, including CNC machining. You might be wondering if the anodizing process helps CNC machining. The answer is YES. It, one way or another, supports the CNC machining of aluminum.

 

Anodizing aluminum in CNC machines is a key step that determines durability. It also builds resistance and insulation for effective outcomes. Additionally, the Aluminum CNC machining service providers achieve superior surface finish. They can make custom parts with the desired thickness.

 

Frequently Asked Questions 

 

Which is the best electrolytic solution for aluminum anodization?

I consider Sulfuric acid to be one of the best electrolytes. It is eco-friendly and cost-effective. Additionally, it helps in achieving a thicker oxide layer with excellent durability.

 

What is the difference between anodizing and electroplating?

Electroplating means adding a metal layer to another metal. On the other hand, anodizing refers to forming a protective shield. This shield just protects the surface of different metals from corrosion. The only common thing is that both methods use electricity to complete the reaction.

 

Are anodized parts durable?

Indeed, yes! Anodization adds resistance and finish to the metal surface. So, the metal becomes rigid and can withstand rigorous wear and tear in various realms.

 

Can I double-anodize the same aluminum?

Yes, you can do that. However, remember that double anodizing the same aluminum will impact its thickness and strength.

 

Is anodized aluminum safe?

Yes, there are no such health risks with anodized aluminum material. It is safe for versatile applications. It is used in medical devices, automobiles, aerospace, and other industries.

 

Is Anodizing Expensive?

Not at all. Anodizing is cost-effective compared to other finishing methods. Unlike painting or electroplating, it lasts longer. At the same time, it gives the metal a pristine shine that is irreplaceable in the long term.

 

How do we verify the quality of anodized metal?

You may conduct different tests to verify the quality of the anodized metals. For example:

• Hardness Testing
• Corrosion Resistance Test
• Poros Quality Test

 

Which are the metals that can’t undergo anodization?

Certain metals, such as carbon, iron, and copper, can’t undergo anodization because they cannot form a stable oxide layer. Other metals, such as titanium, zinc, Tantalum, and magnesium, can undergo this process.

 

Conclusion 

 

Ultimately, the anodization process is helpful and works like a charm. Metal such as aluminum can benefit from this. As you know, aluminum is prone to corrosion. Its natural oxide layer is not durable and attractive. However, the aluminum anodizing process adds a robust and aesthetically pleasing layer.

 

But that’s not the end. The added aluminum oxide layer also keeps the paint on it for a long time. This means that if you paint anodized aluminum, it will keep the color for a long time. On the other hand, the original aluminum layer does not hold the paint coat. I’ve given all the nitty gritty of the aluminum anodization process. It is your decision about whether you should use it or not.